if a<0, then you of course have one such positive x, at least x→ +∞
If a>0, you must have D>0, and also atleast one of the roots must be positive..atleast one of the roots will be positive if a-3<0 i.e a<3(note that here both the roots will be positive with the conditions)
and D>0 gives (a-1)(a-9)>0, a>9 or a<1, we had a<3 so that 0<a<1
so a \in (-∞, 1) - {0}