ligand field splitting

JEE Main 2015 Coaching › Inorganic Chemistry questions › ligand field splitting

surrounding groups affect the energy of some of d orbital more than the others. thus, the d orbtals are no longer degenerate- why should surrounding groups affect the energy of some d orbital more than the others when they r previously degenerate??

#Chemistry #Inorganic Chemistry #Group 3 - 12 (Transition Elements & Co-ordination Chemistry

UP 0 DOWN 0 0 1
Post on FacebookPost anonymously?

1 Answers

Manish Pankaj ·2014-06-24 03:30:26

As a ligand approaches the metal ion, the electrons from the ligand will be closer to some of the d-orbitals and farther away from others causing a loss of degeneracy.See if ligand approaches in an axial direction they will encounter first the electron cloud of d(x²-y²) and d(z²) orbital.so the replulsion causes increase in energy as compared to that in d(xy),d(xz),d(yz) orbital.see figure

UP 1 DOWN 0
Post on FacebookPost anonymously?

Your Answer

Basic Integral Calculus Operators Symbols Matrix Cases

√ √ || {} [] () → ~ ^ x x x → → ln log lg lim lim cos sin tan cot arcsin arccos arctan

∫ ∫ ∫ ∫ ∫ ∬ ∬ ∬ ∬ ∬ ∭ ∭ ∭ ∭ ∭ ⨌ ⨌ ⨌ ⨌ ⨌

∑ ∑ ∑ ∑ ∑ ∮ ∮ ∮ ∮ ∮ ∏ ∏ ∏ ∏ ∏ ∐ ∐ ∐ ∐ ∐

+ - × ÷ ± ∓ = ∪ ∩ ≠ ∼ ≈ ∅ ∀ ∃ ∈ ∋ ∝ ≤ ≥ ≃ ≅ ≡ < > ≪ ≫ ⊂ ∉ ⊃ ⊆ ⊇ ⇒ ⇐ ⇔ ⇒ ⇐ ⇔ ⇑ ⇓ ⇕ → ← ↔ → ← ↔ ↑ ↓ ↕ ↖ ↗ ↘ ↙ ↪ ↩ ⇀ ↼ ⇁ ↽

° ∂ ∞ α β γ δ θ λ μ ν ξ π ρ σ φ ω ε ƒ κ τ υ Γ Δ Λ Σ Π Ω

Close [X]

ligand field splitting

1 Answers

Your Answer

Add Image

Similar Questions