Reasoning + Multiple objective

1. Statement-1: In diamond carbon atoms occupy alternate tetrahedral voids in the FCC lattice formed by the carbon atoms
Statement-2: In diamond, packing fraction ismore than 74%.

2. Which of the following properties of themetal gets changed due to formation of interstitial carbide.
(A)Density (B)Hardness (C)Malleability (D)Electrical conductivity

8 Answers

1
rahul1995 yadav ·

1..i think statement 2 is false

29
govind ·

For the first one..carbon forms a Wurtzrite Structure similar to that of ZnS..so the packing fraction will be greater than 74% ...but the second statement is not a correct explanation of first..so i go with B..

Ans2..i think the answer shud be A,B and C ..
as the carbon atoms occupy the voids so density shud increase..

11
Devil ·

Govind, 2 A) is ok, how do u explain b) & c) ?

29
govind ·

In the second question u can take the case of iron and steel...pure iron is soft and steel is hard..so i took this case for options B and C...not sure of the answers...maybe i am right..

1
Great Dreams ·

@govind its not wurtizite but zinc blende type
and we can compare both structure due their geometry
in diamond C is tetrahedrally surrounded by other C's so is the case ZnS (blende) it is fcc packing with Zn2+ occupying alternate tetrahedral voids
so i think reason is falsese because packing fraction >74%

1
Tapas Gandhi ·

@govind
steel is not a carbide but say cementite Fe3C
@Soumik
WC tungsten carbide is a very hard substance (edited)
WC is an abrasive (editedx2)

so>>>>A,B,C
electrical conductivity remains comparable

29
govind ·

Ya diamond forms ZnS zinc blende structure..but in rare cases forms wutzrite too(dont worry that's an exception)..but why statement 2 is false Tom?

@Tapas..i meant Fe3C only..that's an important component in steel's manufacturing..

1
Tapas Gandhi ·

WURTZITE STRUCTURE (Wikipedia)

The wurtzite group includes: Cadmoselite CdSe, Greenockite CdS, Mátraite ZnS and Rambergite MnS, in addition to wurtzite.

Diamond Lattice

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