Organic Chemistry - A to F identify

24

eureka123 ·2009-10-05 10:57:18

sad that no one trying this ........[2]

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aieeee ·2009-10-06 02:16:00

i hv tried it and F am getting CH₂=CH- C =OCH₂-CH₂-COOCOCH₃.
but a bit doubtful abt it. plz confirm.

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eureka123 ·2009-10-06 02:56:21

a bit wrong...
F : CH₂=CH-CH-CH₂-CH₂-C-O-C-CH₃
l ll ll
OH O O

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aieeee ·2009-10-07 11:31:45

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$ourav @@@ -- WILL Never give ·2009-10-07 16:34:55

aieee,can u explain d last step in conversion...why is it cleavaging at dat point???

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msp ·2009-10-07 19:47:29

can ne1 explain me the A product.

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aieeee ·2009-10-10 11:26:02

@msp - PCC oxidises alcohol to aldehyde

@ maths... - C=O IS A EWG.

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$ourav @@@ -- WILL Never give ·2009-10-10 19:08:16

thanks i understood...,but why are u changing d second -C=o from d right in product f.....it should have remined -C-OH as in product e....coz dere is no oxidising agent....plz reply

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aieeee ·2009-10-10 21:29:14

dude , from E , when -OH group is eliminated , dat time this carbonyl group is formed ; this is becoz -OH is a not a very good leaving group , dats why its first protonated and eliminated.

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A to F identify

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