Alcohol doubt 2

8 Answers

1
Ankur ·

break the bond and oxidize..

19
Debotosh.. ·

the bond with adjacent OH groups undergo cleavage /////thats it [4]

106
Asish Mahapatra ·

the bond between vicinal diol (pinacol) will break and the product will be the one assuming there was a double bond where the two -OH are there and u are doing oxidative ozonolysis

39
Pritish Chakraborty ·

Tushar, have they shown what conformation(cis or trans) the diol is in?

106
Asish Mahapatra ·

@pritish, is there any stereochemical restriction as well here?

39
Pritish Chakraborty ·

HIO4 oxidises only cis diols, while lead tetraacetate oxidises both cis and trans diols, that's why.

11
Tush Watts ·

@ All , I know the bpnd b/w vicinol diol will break,.

Acc to me , the ans should be

But the ans is given as
????????[2]

@Pritish
Nops, not shown (nothing else)

39
Pritish Chakraborty ·

Ring has contracted? How is that possible...

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