alcohols

Q1 ...Does methylamine (CH3CH2) give alcohol on reaction with HNO2 ?
if not , why ?

Q2... Can we prepare secondary and tertiary alcohols by the action of nitrous acid on primary amines.
if not , why ?

4 Answers

2) I think tertiary alcohol is not possible...

i have to think why!

amine forms an ion by reacting with the acid present.

for example: trimethylamine, you get a trimethylammonium ion, (CH3)3NH+.

Hi RITU, I have corrected first question
Thankz for replying

it forms the diazonium salt , which on addition of water leads to formation of alcohol , 2^oand 3^o is not possible I think .

It's possible , get 1^o alcohol , PCC , then grignard.

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