Organic Chemistry - another org!!! do it :)

1

vector ·2009-02-19 08:14:57

I THINK AT PLACE OF CL IT WILL BE NH2
TELL ME IF I M RIGHT

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21

tapanmast Vora ·2009-02-19 08:17:18

MAYB NOT
ACTIVATOR WINS OVER DEACTIVATOR SO SHUD BE ORTHO TO CH3 but not b/w NO2 n CH3, on the other side...

ans kya hai?

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33

Abhishek Priyam ·2009-02-19 08:21:16

Cl ke jagah par NH₂..

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tapanmast Vora ·2009-02-19 08:43:22

ans batao jadi....

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39

Dr.House ·2009-02-19 08:44:21

no priyam i think u r wrong.

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vector ·2009-02-19 08:45:06

tapan is rite

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11

Sunil Kumar ·2009-02-19 08:45:13

See the intermediate formed can have 2 structures:-

and correspondingly following products can be obtained

Also there is carbanion formation in between so that structure will be favoured which is obtained from most stable carbanion...

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skygirl ·2009-02-19 08:46:33

no richa u are right..

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skygirl ·2009-02-19 08:47:35

well sunil... which form do u think is most stable ?

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11

Sunil Kumar ·2009-02-19 09:01:18

In my view the NH₂ will be at place of Cl cause NO₂ group is -I group hence it can stabilise the carbanion formed but on the other hand it is also a deactivating group.

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vector ·2009-02-19 09:03:11

i just thought dat as m effect dominate over H n I Effect so it ll be favoured to get rid o f -m of no2

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skygirl ·2009-02-19 09:04:05

no..

sunil is EXACTLY correct ..

pink to you ..

bhaiya kal bana denge ...

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Sunil Kumar ·2009-02-19 09:05:31

Thanks.......

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another org!!! do it :)

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another org!!! do it :)

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