Ans not matchin

BITSAT Guidance › Organic Chemistry questions › Ans not matchin

The following compound

treated with AgNO₃ and H₂O ??

#Chemistry #Organic Chemistry

UP 0 DOWN 0 0 9
Post on FacebookPost anonymously?

9 Answers

39

Pritish Chakraborty ·2009-10-27 02:21:07

In place of Iodine you will get -OH group, and Ag will abstract the halogen atom and form a precipitate. AgI ppt is insoluble in ammonia solution of any concentration, that's how you test for it.
Thus you will get HNO₃ and AgI as byproducts.

UP 0 DOWN 0
Post on FacebookPost anonymously?

11

Gone.. ·2009-10-27 02:25:16

thats what even i got..but thats not the ans given .

UP 0 DOWN 0
Post on FacebookPost anonymously?

39

Pritish Chakraborty ·2009-10-27 02:34:56

Well the carbocation cannot rearrange to a secondary one as the bridge head carbon cannot be planar. But Ag will leave primary carbocations with no mercy, the mechanism will go forward. Can you post the ans?

UP 0 DOWN 0
Post on FacebookPost anonymously?

11

Gone.. ·2009-10-27 02:38:54

ok..wait a sec

UP 0 DOWN 0
Post on FacebookPost anonymously?

11

Gone.. ·2009-10-27 02:41:23

UP 0 DOWN 0
Post on FacebookPost anonymously?

39

Pritish Chakraborty ·2009-10-27 02:41:52

Maine toh yahi kaha tha?? iodine ke jagah -OH?
Ahh..wahan pe rearrangement kaise hua?

UP 0 DOWN 0
Post on FacebookPost anonymously?

11

Gone.. ·2009-10-27 03:18:22

how did xtra carbon come ??

UP 0 DOWN 0
Post on FacebookPost anonymously?

39

Pritish Chakraborty ·2009-10-27 04:52:43

Wahi..possibly a misprint?

UP 0 DOWN 0
Post on FacebookPost anonymously?

11

Gone.. ·2009-10-27 05:50:30

okie...

UP 0 DOWN 0
Post on FacebookPost anonymously?

Your Answer

Basic Integral Calculus Operators Symbols Matrix Cases

√ √ || {} [] () → ~ ^ x x x → → ln log lg lim lim cos sin tan cot arcsin arccos arctan

∫ ∫ ∫ ∫ ∫ ∬ ∬ ∬ ∬ ∬ ∭ ∭ ∭ ∭ ∭ ⨌ ⨌ ⨌ ⨌ ⨌

∑ ∑ ∑ ∑ ∑ ∮ ∮ ∮ ∮ ∮ ∏ ∏ ∏ ∏ ∏ ∐ ∐ ∐ ∐ ∐

+ - × ÷ ± ∓ = ∪ ∩ ≠ ∼ ≈ ∅ ∀ ∃ ∈ ∋ ∝ ≤ ≥ ≃ ≅ ≡ < > ≪ ≫ ⊂ ∉ ⊃ ⊆ ⊇ ⇒ ⇐ ⇔ ⇒ ⇐ ⇔ ⇑ ⇓ ⇕ → ← ↔ → ← ↔ ↑ ↓ ↕ ↖ ↗ ↘ ↙ ↪ ↩ ⇀ ↼ ⇁ ↽

° ∂ ∞ α β γ δ θ λ μ ν ξ π ρ σ φ ω ε ƒ κ τ υ Γ Δ Λ Σ Π Ω