Aryl Halide ( tell product )

pls tell the product...

1. Mg/ ether (excess)
__________________
o-Bromobenzyl bromide ?
2. H2O

25 Answers

1
RAY ·

it needds angle of 120* and is having only 60*

11
virang1 Jhaveri ·

ok now think if it was not mg/ether in excess. Then which Br will be attacked will be important

1
kartik sondhi ·

It remains the Same 'Toulene'

11
virang1 Jhaveri ·

No the answer will be
p-methyl Benzene

Since first it forms a grignard reagent and in G.R mgX have a positive charge
Therefore it will form first carboanium ion and then react with H+

1
kartik sondhi ·

I think this Will be the correct answer

1
RAY ·

grignard causes a - charge n then since water is there...H+ is taken...simple:0

1
RAY ·

then it is rather more easy..just remove the br and put H...i dun think there is any chance of forming a three member ring!!

that was mah post no.8 n i too gave the same product..[:P]

1
$ourav @@@ -- WILL Never give ·

its just toluene....a simple 1

1
shreya ·

yes.. the answer is correct.

can u pls explain how/why u did it??

24
eureka123 ·

u missed ether there in reactant

1
shreya ·

No...

i dont hve the answer

1
RAY ·

yes ...dont u hav the answer???

1
shreya ·

ok... may be.

i dont know, i thought this should be correct as it was a dihalide.

1
RAY ·

1
RAY ·

i dun think so..i though of dis onen i mentianed in mah previous post that thiswill unstable due to the strain!!though m not very much sure

1
shreya ·

tell if dis is correct

1
RAY ·

u cannot have a alkyne since the strain in d benzene ring will be tooo much then!!

1
RAY ·

arre i meant that onnly that it will form grignard wid Mg...n Mg/ether is called grignard reagent!!

1
shreya ·

Mg is not grignard. Grignard is RMgX.

with the help of Mg and dry ether along with alkyl halide we form grignard reagent.

1,2 dihalide's rxns give alkenes ( here, 1,2 dihalide alkene type rxn gives alkyne ) with Mg/ether.

1
RAY ·

then it is rather more easy..just remove the br and put H...i dun think there is any chance of forming a three member ring!!

1
RAY ·

benzoine intermediates reaction doesnt occus...n here if wht u r telling is right shreya then WHY HAVE THEY GIVEN EXCESS GRIGNARD???

1
shreya ·

it is

1
shreya ·

the reactant u hve taken should react lik dis

1
RAY ·

ortho bromo benzyl bromide..whts the structure???

1
shreya ·

check the ques. its o - bromobenzylbromide

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