better acid??

which solution is a stronger acid.
HCl dissolved in water or HCl dissolved (unionised) in benzene???

17 Answers

1
sriraghav ·

I think above two may be the possible reasons....maybe not the exact one

1
rickde ·

thanks i understood it

1
JOHNCENA IS BACK ·

look we are not comparing strength of HCl in two different solvents.we are comparing strength of the two solutions...........y r u not reading this line properly

moreover,i wrote add water to explain clearly.........it is not unneccesary!!!!!!!!!!!!!!!

if u will words i made bold u will get the core concept of problem!!!!!

look if u got now!!!!!!!!!!

1
sriraghav ·

then is only when u add water.....

note...solution doesnot mean that the solvent is water.... , in case 2 benzene is the solvent

Why are u adding water unneccesarily, to compare acidity??

1
JOHNCENA IS BACK ·

@sriraghav

y not satisfied!!!!!!!

okay.....do one thing

read posts in this order #12,then#7and finally #11......then reply!!!!!!!!

1
sriraghav ·

still not satisfied john!!lets wait for others..

1
JOHNCENA IS BACK ·

@sriraghav and rickde

got it now???????????

1
JOHNCENA IS BACK ·

@sriraghav

read the question properly!!!!!!!!!

they r not asking when HCl will be more acidic.

instead they r asking which solution will be more acidic..

1
JOHNCENA IS BACK ·

bhai..............

after this let me try more .......

since HCl in solution 2 in not yet ionised wat do u think will happen if u add some water to it??????????

it will ionise....right.........i.e.solution 2 is more acidic

now do same with solution 1!.....wat do u conclude

clearly,now i think everything shud be crystal clear!!!!!!!!!!!

1
rickde ·

boyd and morrison ka question hai.
ans HCl in benzene diya hua hai

1
sriraghav ·

yes rickde, i agree wit u..

@!john.....if an acid furnishes more H+ ions in the solvent more it is acidic....What is the specific reason??

May be common ion effect more predominent in Hcl in water will reduce H+ dissociation??

Hcl is partially polar,ie it is between polar and non-polar nature.... there fore it increases it's dissociation in bensene(partial non-polar nature is due to high electronegaticity of cl atom)

1
rickde ·

but HCl if it does not ionise how can it give H+
isn't it the reason due to which dry HCl does not give litmus test????
i'm still confused

1
JOHNCENA IS BACK ·

@rickde your ans. is directly given in question itself.

in solution 1 i.e.HCl dissolved in water HCl is dissociated into ions.....so the resulting solution is not a strong acid.

in solution 2i.e.HCl dissolved (unionised) in benzene.i.e. HCl is not dissociated in benzene..........so resulting solution is a strong acid.

got it now??????????

1
rickde ·

but why is that so????

1
JOHNCENA IS BACK ·

ya........mr.morrison is right(absolutely)

i din read this line of your question in a hurry

which solution is a stronger acid.
HCl dissolved in water or HCl dissolved (unionised) in benzene???

solution of HCl dissolved(unionised) in benzene is stronger acid!!!!
hope u got it!!!!!!!![1]

1
rickde ·

why is that so????

1
kamalendu ghosh ·

HCl dissolved in benzene

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