yep... ofcrs..
OEt is better leaving grp than NH2-.. shak tha?
all that matters here in this question is the diff in leaving groups ..
yep... ofcrs..
OEt is better leaving grp than NH2-.. shak tha?
all that matters here in this question is the diff in leaving groups ..
not funny.serious.......change pic yaar put ur clear photo[3][3][3].....
haan mujhe yaad nahi tha.... wo to tukka tha mera answer between
4312 and 4321
@matrix... yaha q discuss kar rahe hai sab... aur tu mera photo discuss kar raha hai.. [3]
well i know 4 and 3 hav great compition but i think 3 wins
do correct me
OMYGOD!!! I DID A BLUNDER.....
IT IS 3>4>1>2 ......
ACTUALLY COPY ME JIS ORDER PE Q LIKHA THA.. MAIN US ORDER MEIN NAHI LIKHI YAHAN PE.... ISILIYE ALL THIS...
SOORY ABHISHEK U WERE WRONG....
AND SORRY VISHAL U WRE RIGHT..
PHY KARTE WAQT CHEM KARNE SE YAHI HOTA.........
isiliye maine poocha tha... acidic ya basic...
in acidic 4>3
ain basic 3>4
because in 4 in acidic medium it protonates ....
pata nahi ye bhi galat hi hua hoga... :(
mera aaj dimmag thik nahi hai.. :'(
look at the conjugate acids :
HCl and EtOH......ethyl alcohol is a weak acid and hence has a stronger conjugate base than hydrochloric acid !....we know that leaving tendency is inversely proportional to basicity....hence OEt- is a sronger leaving group than Cl-
the reasons i think are that
1. Cl- has more polarisability than OEt-.
2. CH3CH2------ gp is bulky hence it inc the basic strenghth of EtO-
ek question yaad aya:
arrange in inc order of hydrolysis..
1) CH3-COO-Cl
2) CH3-COO-OEt
3) CH3-COO-Me
4) CH3-COO-NH2