cant undrstand mechanism

can u pls help me out in understanding the mechanism of preparation of alkanes using LiAlH4 and alkyl halide....... y can't LiAlH4 be used with 3° halide???

what is the compound (n-C4H9)3 SnH ??

2 Answers

1
Ronald Clement ·

I think the compund you are talking about is Ph3SnH . it is used instead of LiAlH4. Then the rxn. simply follows Free radical mechanism.

The 1st one i think follows SN2 mechanism...not sure though.Now y it is not applicabe for tertiary alkyl halide is clear.. u got it ??

1357
Manish Shankar ·

Ronald is correct

LAH and alkyl halide follows SN2 mechanism
tertialy being crowded do not give SN2 reactions

but with (n-C4H9)3 SnH it goes free radical mechanism
so tertiary halide can be reduced using this

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