Organic Chemistry - decarboxylation

1

mkagenius ·2009-02-14 22:05:09

it will give a salt...(acid base neutralisation)

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rahul wadhwani ·2009-02-14 22:05:13

thinking 2-nitro toluene is it correct

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1

mkagenius ·2009-02-14 22:06:03

u told just to react it with naoh.....

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1

mkagenius ·2009-02-14 22:07:02

toluene kahan se aa gaya......[3]

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1

vector ·2009-02-14 22:10:51

ans is nitro methane

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vector ·2009-02-14 22:12:59

wat s d mechanism

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11

Sunil Kumar ·2009-02-14 22:13:09

ya it is not nitroethane..
it will be nitromethane.

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1

vector ·2009-02-14 22:14:04

it s nitro methane but how

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mkagenius ·2009-02-14 22:14:34

co2 goes away .....rest gets converted to alkane

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mkagenius ·2009-02-14 22:14:59

its in the ncert

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mkagenius ·2009-02-14 22:15:24

r u bothered abt nitro...

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1

vector ·2009-02-14 23:31:51

wat ll happen if cyano instead of nitro

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1

skygirl ·2009-02-15 20:07:15

arey its decarboxylation again!

CO2 leaves...

even if its -CN, same thing only...

remember : ANNNNY -I GROUP GIVES WAY TO STABLE DECARBOXYLATED PRODUCT ...

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24

eureka123 ·2009-02-15 21:01:54

gud concept sky......[1]

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1

Grandmaster ·2009-02-15 23:49:43

just from the question's perspective

1.i don't understand why no2-ch2-cooNa will not be formed

2.and how without mentioning soda-lime decarbolxylation took place(although NaOH) is present

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39

Dr.House ·2009-02-15 23:59:15

@ abhishek: there are two types of carboxylation

one is by NaOh and Cao

and other is by kolbe`s electrolysis. so if anyone says NaOH It is taken to be soda lime carboxylation.

tell me if u know any other carboxylation using NaOH.

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