Organic Chemistry - intermediate

24

eureka123 ·2009-02-14 03:53:30

ok.....i will draw it and u tellll if its teh same as urs....

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39

Dr.House ·2009-02-14 04:22:44

wat man? link for evrything?????????

by the way ws i right?

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1

voldy ·2009-02-14 04:21:07

shit I forgot mechanism . well it contains both FR and carbanion.

here'e sthe link.

http://en.wikipedia.org/wiki/Birch_reduction

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39

Dr.House ·2009-02-14 04:01:54

@eureka: then will other carbon go to hell? it should also have a single electron on it na. think bhai think.............

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39

Dr.House ·2009-02-14 03:59:57

@abirup: there is need of whisky dude, not alcohol.

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13

Ð”Ð²Ò¥Ñ—ÑuÏ now in medical c ·2009-02-14 03:59:44

i think both are right....

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1

voldy ·2009-02-14 03:59:42

no!it's FR process

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24

eureka123 ·2009-02-14 03:57:33

mathie.....explain hows it?????

i thought like this

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13

Ð”Ð²Ò¥Ñ—ÑuÏ now in medical c ·2009-02-14 03:55:55

is n't there a need of an alcohol here[7] like EtOH

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39

Dr.House ·2009-02-14 03:55:54

yup right.

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voldy ·2009-02-14 03:43:12

no reaction.

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39

Dr.House ·2009-02-14 03:51:02

i am lazy to draw but whatever i gave damn sure that i am right.

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39

Dr.House ·2009-02-14 03:50:32

after NH3 adds , its a free radical
CH3-C^(.)=CH3

the second carbon is a carbon with a single electron

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24

eureka123 ·2009-02-14 03:49:47

cant understand............draw it plzzzzz..i am getting it wrong......book says something else....

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1

voldy ·2009-02-14 03:49:07

fr process

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39

Dr.House ·2009-02-14 03:48:59

the intermediate before NH3 acts is CH3-C=C^---CH3

THERE IS A NEGATIVE CHARGE ON THE THIRD CARBON FROM RIGHT

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24

eureka123 ·2009-02-14 03:48:59

yup birch reduction/.........

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24

eureka123 ·2009-02-14 03:48:40

reaction definitely takes palce.........thats why asking intermediate......[3]

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1

voldy ·2009-02-14 03:48:38

oh sorry , this is birch reduction no ? my mistake dunno why It thought os NaNH₂ .:P

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39

Dr.House ·2009-02-14 03:44:15

wat srinath????????????????????????????????? dont we get a alkene?

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