1357
Manish Shankar
·2008-11-05 12:21:45
The reactivity should decrease as it will reduce the positive charge on the carbon atom
1
big looser .........
·2008-11-05 12:28:53
but + I effect will increase the + positive charge on carbon
1357
Manish Shankar
·2008-11-05 12:33:26
I think you are confudsed
+I are electron releasing which will decrease the +ve charge on carbon
1
big looser .........
·2008-11-05 12:38:48
oh sorry
but reducing + ve charge will increase the stability of carbocation and its formation will become easier so, don't you think that it will increase the reactivity
1
°ღ•๓ÑÏ…Î
·2008-11-05 12:40:02
hmmmmmmm...........
nucleophile is lewis base means itz eltron rich so it attckes carbon .....of d carbonyl compund coz it has positive chrge
wen d eltron donatin susbtituents increse d positive chrge on carbon whm d nucleophile will attck will decrese as positve chrage decrese d rxtivity decrese
corrct me if m wrng :'(
1357
Manish Shankar
·2008-11-05 12:43:20
integrations you are absolutely right
1
big looser .........
·2008-11-05 12:52:14
i am still confused .. wats wrong in my statement
1
°ღ•๓ÑÏ…Î
·2008-11-05 13:00:11
hey b y u need d stability of carbon
wat we need is d chrge on nucleophile and carbonyl carbon so bas
jab woh carbon par charge decraese hoga .nucleophile will nt b dat attrcted 2wrds it as it wud hav been if d charge wud hav had remein intact or say charge on crabon wud ahv has incerse(+ve)