Man !!! It's Organic again !!

Indicate the bond energies of C-H bonds indicated by a, b ,c in ascending order.

Please give reasons.

10 Answers

1
nikunj ·

a=vinyl
b=Allyl
c=Methyl

c>a>b

1
Bicchuram Aveek ·

ANS given is : b < c < a .

1
nikunj ·

Bond Hydrocarbon radical Bond Dissociation Energy (kcal/mole)
CH3-H Methyl 103

CH2=CH-H vinyl 112

CH2=CHCH2-H Allyl 88

http://en.wikipedia.org/wiki/Carbon-hydrogen_bond

1
nikunj ·

a>c>b

1
nikunj ·

Typing error in post2 .

39
Dr.House ·

bond dissociation energy of methyl is always greater than the allyl group..

and obviously c has highest ..

so b<c<a is true

1
Bicchuram Aveek ·

Can someone please give the reason why this is so that B-E of methyl > allyl > vinyl ??????

39
Dr.House ·

aveek.. u try reasoning out dude... the ease of removal of hydrogen...

then u can get the asnwer yourself :)

1
Bicchuram Aveek ·

IS IT +I EFFECT ?

1
madhumitha harishankar ·

http://targetiit.com/iit-jee-forum/posts/ohh-god-organic-x-14844.html

i think u and subhomoy are using the same book, and having the same doubts! :P

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