1yes !... siddhart !!
anyhow the mightier will survive !
its the law of nature !
the weak is indeed replaced by the strong ! :)
in this case its nucleophile !
"nucleophilicity runs parallel to basicity when the nucleophilic atom is the same in various species"
-
UP 0 DOWN 0 0 97
97 Answers
1subash do you have anything to discuss?
i mean i was doin some physics ......lets do physics today !
or will continue this stuff tomorow !!
what do you say ?
1
1You are absolutely wrong.
Let me reproduce from the text book.
"(5) In nucleophilic substitution reactions basicity of leaving group should be less than the basicity of incoming nucleophilic group. Thus strong basic nucleophilic group replaces weakly basic nucleophilic group of the substrate"
Modern Organic Chemistry by Jagadamba Singh ---page 212
1there are many . I'll only tell why . if it's a strong base it prefers to abstract a protn than go and attack somehwere hope u got it.
3unique anna OH- is a good nucleophile than HS-
BECOS THE MOLECULE SHUD LIKE
11ya rite tomorrow nite same time i will come with some thing to discuss as well
1so did u guys gain any ??
we will continue it tommorow with some interesting things !!
after all discussion plays a major role in JEE :)
1iam (very)1/0 poor in chemistry so i wnat to gain some information through this discussion
11i am (very)infinfiy poor in chemistry
i joined this discussion just because i thought i could learn something from this
1subash for the sake of discussion ! :)
i am very very very very very very very very very very poor in chemistry !!
hehe .. even worst than this !
1throw the bonds away prajith!!
hehe ...the second reason was healthy though!
good work !
11itz okay they are different terms
but one can atleast say nucleophilicity is proportional to basicity
btw r u asking these questions as doubts or discussions
1prajith ofcourse it is !! if OH isnt stronger then , obviously HS is !!
intelligent boy ! :)
but reason please !
3charged ions can attack the positively charged atom more effectively than the uncharged ones
3ok unique then the
order will be RO->RCOO->ROH > RCOOH
a good nucleophile is one which has more tendency to attack the positive charged ion.
the alkoxide ion have more electron density than other molecule and therefore it has the more probability to attack an electrophilic center becos negative charge will spread more over the molecule
1u are wrong guys !! ...thats why i did post this one !!
please ponder over !