plz answer

5 Answers

1
aieeee ·

Cl2 + H2O → HCl + [O]

So , there are two possibilities :

i) the double bond splits
or
ii) CCl3- is extracted out.

but the 2nd case is not favourable as a vinyl carbocation is formed.

thus , we go with first step and H+ attacks 2nd carbon as its stabilised by CCl3- and the other carbon is attacked by Cl-.

thus product is : Cl3-C-CH2-CH2-Cl

39
Pritish Chakraborty ·

No halohydrin formation...?

1
hacker ·

@ aieeee plz check ur chtbx yaar!!!!!

1
aieeee ·

I think perhaps no. becoz if halohydrin reaction takes place , then Cl would be added to 2nd carbon and OH to 3rd carbon. thus :

i) there would be hindrance for a large group like Cl to be inserted

ii) lone pair - lone pair repulsion of four Cl groups

39
Pritish Chakraborty ·

Hmm you're right!

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