Product prediction

Find the product..........

HC≡CH→(CH3MgBr) A
A→(CO2,H3O+)B
B→(HgSO4+H2SO4)C
C→(Ag2O) D
FIND D

ans.acetic acid

1 Answers

39
Pritish Chakraborty ·

The first product A is formed because the terminal hydrogen of ethyne is acidic. A => H-C≡C-MgBr and the byproduct is methane.
Then the Grignard is used in the standard way to produce a carboxylic acid. B is H-C≡C-COOH.
The next reaction focusses on hydration and tautomerization of the alkyne part. C is H3C-C(=O)-COOH.
Not sure what D would be...don't remember Ag2O action.

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