some dbts in nomenclature

26 Answers

24
eureka123 ·

@kartick....
alcohol has higher priority that amino acids...

106
Asish Mahapatra ·

can u give the examples??

23
qwerty ·

actually me 2 having a few doubts ..normally alkenes are given preference over alkynes while selecting functional grp ...i came across few compounds ....where alkyne was given preference ..just bcz the triple bond was a terminal one ....
I think nomenclature is far more vast than our syllabus ...so IIT wont ask complicated stuff....

106
Asish Mahapatra ·

hmm answer was given as 3-ethyl, 5-iodoheptane

13
Avik ·

5-Ethyl-3-iodoheptane..

106
Asish Mahapatra ·

then what abt this one?

23
qwerty ·

in that iodine will be given priority ...u will hav to go in alphabetical order ....in ...Methyl and Iodine .. I is b4 M hence Iodine is named b4 methyl

23
qwerty ·

Q.6 : halogen grps arent treated as functional groups ....
for eg: 1-chlorobutane, 2-bromopentene.....etc...actually there is a priority order of functional grps ....

1] Carbocations
2] Carboxylic acid
3] Acid anhydride
4] Esters
5] Acyl halides
6] Amides
7] Nitriles
8] aldehydes
9] Ketones
10] Alcohols
11] Thiols
12] Amines
13] Ether
14] Sulphides
15] Alkenes
16] Alkynes
17]Alkanes
18] Alkyl halides
19] Nitro grp

PS: someone confirm if it is correct

3
msp ·

first one bcos iodine shud be given high priority and its in the longest chain.

106
Asish Mahapatra ·

Q7.

IUPAC NAME? ?

5-ethyl,2-iodoheptane

OR

2-ethyl, 5-iodoheptane

106
Asish Mahapatra ·

Q4. Kartick is correct

1
kartick sharma ·

amide has higher priority acc. to NCERT 11th pg. 336 !!!!!!!!!!!

11
Gone.. ·

When my tuition sir taught he discussed both the compounds..i just checked up the copy..even he said --
1. 3-carboxypentane-1,5-dioic acid
2. 3-cyanopentane-1,5-dinitrile

1357
Manish Shankar ·

1) Propane-1,2,3-tricarboxylic acid

1
kartick sharma ·

Q 4)

2-ethenyl-4-hydroxypentanamide

11
Gone.. ·

kartick is talking about citric acid--

http://en.wikipedia.org/wiki/Citric_acid

1
kartick sharma ·

satisfied with manish sir , IF IT IS THE COMP. THEN

THEN IT'S NAME WILL BE:
2-hydroxypropane-1,2,3-tri carboxylicacid

24
eureka123 ·

Q4
4-methanamide-hex-5-en-2-ol

I ma not 100%sure abt this

11
Gone.. ·

in my school book Succinic Acid is 1,4-butanedioic acid...c this

http://en.wikipedia.org/wiki/Succinic_acid

has IUPAC revised its nomenclature regarding this ??

ur name is in "Other names" there

24
eureka123 ·

Q3
2-ethenyl-pentamide

24
eureka123 ·

for ronald...Q1
if the compound contains more than 2 acid functional groups,the longest alkyl chain containing max no. of carboxy functional groups becomes parent chain and C00H groups are treated as locant.Preference in numbering given to COOH group [1]

1357
Manish Shankar ·

CN is name in the same way

its propane-1,2,3-tricarbonitrile

11
Gone.. ·

i think one is 3-carboxy pentan-dioic acid. (take longest chain)

106
Asish Mahapatra ·

but then why is it not the same for the CN groups

1357
Manish Shankar ·

here the priority is same for these functional groups and each group contains carbon, thats why it is con considered as secondary group

106
Asish Mahapatra ·

sir, but isnt the first rule to select the longest C-atom chain?

in that case shudnt the name be 3-carboxy pentan-dioic acid?

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