stuck in organic...help urgently!!

Q: why is sulphuric acid not used during reaction of alcohols using KI??

umm....generally we use it like:

R-OH + NaBr + H2SO4 ----> R-Br + NaHSO4 + H2O!!

7 Answers

1
madhumitha harishankar ·

Sulfuric acid could cause the competing reaction, elimination, to occur giving impurities of alkene with your desired reaction products

the reaction would also be explosive.

·

NCERT ques

1
The Enlightened One - jsg ·

no..i dont think that is the answer..I think it is beacuse in the case of Iodine..sulphuric acid CAN act as AN OXIDISING AGENT..so eventually Iodine escapes as I2 !

1
The Enlightened One - jsg ·

and that is why we use acids like H3PO4 ...

1
cute_cat ·

yups js genius is right....sulphuric acid acts as oxidising agent.....and oxidises strong reducing agent HI to I2 (which is therefore producd using KI and H3PO3)

also reaction could b explosive

and what madhumita has mentioned about the products being elimination products...is actually the reason why sec and tert bromides and iodides cant b prepared by using sulfuric acid

39
Pritish Chakraborty ·

Wow yaar...everyone has become self sufficient in organic...:P

1
The Enlightened One - jsg ·

Pritish..u were the one who started it all !!! [1]

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