TRY THIS

Q)

10 Answers

24
eureka123 ·

is the product an enol ??

not so sure..but plz reply

1
aieeee ·

ya , its a tertiary alcohol. dude , plz give ur mechanism.

i feel ders some migration of aryl group happening , perhaps !

24
eureka123 ·

i dont have mech..
i read a similar thing few days back where cyclization of 1,2 diketos to enols took place....

if i get it i will reply

11
swaraj jena ·

i think this will be the correct mechanism

1
aieeee ·

but swaraj , why is this migration of the phenyl group taking place ?

1
vimalesh mallya ·

Is it??
CH3C(OH)2COPh

1
vimalesh mallya ·

acc to swaraj's mech how can a positive charge come on c next to Ph as it is a electron withdrawing group and destabilises the charge?

11
swaraj jena ·

I hav made som mistek
when OH- will attack attack at this carbon their will formation of - charge on O
but when it returns to its original position there will b posibility of elimination of either Ph group or hydroxyl group.if OH- eliminates ,as the medium is basic so it will again atttack,but if ph group eliminates soon after the elimination OH- will lose an proton immediately. so again Ph cant attack

11
swaraj jena ·

@ vimalesh in my mech shown no where there is formation of +ve charge at carbon .it is an SN2 type reaction .u r right tht Ph will withdo electron and this will increase deficiency at carbonyl carbon and more extent of nucleophilic attack

1
abhimanyubhardwaj ·

is it tertiary alcohol,ch3-ch2-ch2ch3-oh

Your Answer

Close [X]