3
msp
·2009-09-26 00:29:24
i hope that this is not in syllabus.
106
Asish Mahapatra
·2009-09-26 01:11:10
ΔG = -nFEcell
differentiating it wrt T,
d(ΔH-TΔS)/dT = -nF*d(Ecell)/dT
=> -ΔS = -nF*d(Ecell)/dT
=> d(Ecell)/dT = ΔS/nF
now frm the two relations that uve given abv, ΔS = -T[d(ΔG)dT]p
So put in abv equation
Btw, d(Ecell)/dT is known as temp coeff. of the cell
24
eureka123
·2009-09-26 01:11:47
ya its 99.99999% not in syllabus.but i found this ques 2 days back and couldnt work it out..so thought if someone is preparing for olympaid type thing can help me our
106
Asish Mahapatra
·2009-09-26 01:19:32
arey it was taught to us in our insti ,,