unstressed here means that initially the spring is at its natural length and hence no spring force .
due to the field E, a force q.E acts on the body hence it moves outwards causing the spring to stretch and apply a restoring force on the block.hence eventually the block executes shm.
the amplitude can be found easily by finding the distance between points where the force acting is max. and min
hence q.E=k.x
or, x=qE/k=A