24
eureka123
·2009-11-16 23:49:29
Get answer through fajan's rule
1
D Queen
·2009-11-19 04:20:27
@ eureka
I know that but how will i compare Mgo to NaCl??Using charge density??But i dont know how to??
24
eureka123
·2009-11-19 05:32:41
Na^+,K^+,Mg^{2+},Ba^{2+}
Now higher the charge greater is covalency=> \ Melting \ point \ order \ :Na^+,K^+>Mg^{2+},Ba^{2+}
Now if charge same..smaller the size greater the covalency,
\begin{matrix} We \ know \ size :K^+ >Na^+\\ => Covalent \ character \ : Na^+>K^+ \\ => Melting \ point \ :K+>Na^+ \\ => Max. \ melting \ point =KCl \end{matrix}
I hope its clear now...
106
Asish Mahapatra
·2009-11-19 05:36:31
But eure, MgO has max MP i think..
Check up the values
24
eureka123
·2009-11-19 05:39:50
I dont have the values...jsut did it by logic...anyways i will check now..
24
eureka123
·2009-11-19 05:45:00
Ya..the values show opp trend...dont know why[7][7]
1
Unicorn--- Extinct!!
·2009-11-19 06:01:46
I think it has something to do with packing of the molecules in a lattice.
1
sakshi pandey pandey
·2009-11-19 07:57:06
isnt it any application of diagonal relationship bcos li is more covalent than Na & its comparable to Mg .....
1
D Queen
·2009-11-20 00:20:07
Yeah answer is also given as MgO but acc to Fajan it should be KCl..Now why??
24
eureka123
·2009-11-20 04:29:51
thats teh real problem....i dont see anything wrong in my working....so how are we going to do in exam ???
1
D Queen
·2009-11-20 08:41:30
We have to learn some of the things but its gud if anyone can explain this to us
24
eureka123
·2009-11-20 09:13:54
we cant learn MP,BP and oher things of million compounds....there must be some logic...out of thousand other logics in inorganic
1
Unicorn--- Extinct!!
·2009-11-20 21:01:35
None of you think that it is related to packing of molecules?