Hydrogen

Statues coated with white lead on long exposure to atmosphere turn black and the original colour can be restored on treatment with H2O2 .Why ?

5 Answers

1
Arka Halder ·

Due to reaction with atmospheric H2S gas,PbS is formed which is black.
On treatment with H2O2,the black PbS is oxidised to PbSO4 which is white,thus restoring original colour.
PbS + 4H2O2 → PbSO4 + 4H2O.
This is also the same reason as to why old oil paintings are washed in a solution of H2O2 to restore their original colour.

11
Gone.. ·

agree wid arka.

1
Jagaran Chowdhury ·

PbS+4[o=PbSO4

{H2O2=H2O+[O]}*4
______________________________________
PbS+4H2O2=PbSO4+4H2O

this is the complete reaction

1
Jagaran Chowdhury ·

is there any problem with this site??what r these lines... i ddnt make them

1
mentor_Layak Singh ·

yes ..answer is correct !!!!!!!

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