Perhydrol is toh hydrogen peroxide.
1.What exactly is meant by BACK BONDING ?
2.What is Perhydrol ?
3.PBr4 and PI4 doesnot exist according to my theory book and reason given is that Pb4+ is a strong oxidant and Br- and I- are strong reductants [ and so Pb4+ cant exist for long ] ..which is TRUE..but then what about PF4 and PCl4 ???
4.What is a MORDANT ?
5.Does Nitrogen have the maximum/minimum catenation ability in Gp-15..why / why nt ?
6.Explain the following trend in THERMAL STABILITY AND ACIDIC CHARACTER :
HCl03 > HBr03 > HI03 ?
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13 Answers
ya..i know its related to H2O2..but there is some relation based on molarity or something ? [ like volume strength ]
Mordant, I think is a colouring material........yeah, it is a dye. A complex compound.
5. Nitrogen does catenate but to a lesser extent. We've discussed this one before js. An example of nitrogen catenation is N2. But the lack of d-orbitals gives phosphorus the top spot for catenation in group 15.
4. A mordant is something used to dye fabrics such that a complex is formed which attaches to the fabric. It is a metal ion(polyvalent). The complex so formed is colloidal in nature.
Thanks guys but 3 important QUESTIONS are left..pls try to reply to them also..
1. What exactly is meant by BACK BONDING ?
3. PBr4 and PI4 doesnot exist according to my theory book and reason given is that Pb4+ is a strong oxidant and Br- and I- are strong reductants [ and so Pb4+ cant exist for long ] ..which is TRUE..but then what about PF4 and PCl4 ???
6. Explain the following trend in THERMAL STABILITY AND ACIDIC CHARACTER :
HCl03 > HBr03 > HI03 ?
For back bonding one, this might be of some use
http://bama.ua.edu/~kshaughn/ch609/notes/1-structure-bonding.pdf
I found this one tuff!!
1 reason for the 3rd qsn maybe is that Bromine and Iodine are larger in size compared to Fluorine and Chlorine.
So sterically PBr4 and PI4 are unstable.
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ya Soumik..but how can figure out the other two compounds of F an Cl as they have so much reducing power..?...[12]