s - Block

Unpaired electron is present in which of the following species:-
KO2, AlO2-, BaO2 and NO2+
Explain your answer.

2 Answers

333
Hardik Sheth ·

KO2 as it contains O2-

996
Swarna Kamal Dhyawala ·

We can say that with a formula of O2-2, there are simply an odd number of electrons in the anion (6 e- + 6 e- + 1 e- = 13 e- ) . From a molecular orbital explanation, the peroxide ion has a molecular orbital configuration of σ1s(2) σ*1s(2) σ2s(2) σ*2s(2) σ2p(2) π2py(2) π*2py(2) π2py(1) π*2py(1) σ*2p(0). The unpaired electron in the pi* orbital accounts for the paramagnetic behavior or potassium superoxide.

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