Objective question in Electronic Configuration of Elements

Which one of the following sets of quantum numbers represents an impossible arrangement?
~~~~~~~~n~~~~~~~~~~~~~l~~~~~~~~~~~~~m~~~~~~~~~~~s~ a) 3~~~~~~~~~~~~2~~~~~~~~~~~~~~2~~~~~~~~~~~frac{1}{2} b) 4~~~~~~~~~~~~~0~~~~~~~~~~~~0~~~~~~~~~~frac{1}{2} c) 3~~~~~~~~~~~~~2~~~~~~~~~~~-3~~~~~~frac{1}{2} d) 5~~~~~~~~~~~~~3~~~~~~~~~~~~0~~~~~-frac{1}{2}