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Can someone plz explain how and when does ring expansion occur? thanks in advance! ...
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If primary amines are treated with ketones, the product is A. urea B. guanidine C. amide D. Schiff's base ...
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Generally Alcohols r less acidic than water.... (+I & stabilisation of carbanion ..) EXCEPTION : Methanol is slightly MORE acidic than water (pKa 15.5 & 15.7 resp.) Any explanations??? ...
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is there any test on alcohol, ethers????????plzzz do tell me... ...
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when there is a competition between the carbonyl bond and c=c double bond in the case of b.v. oxidation...the double bond gets preference under ordinary conditions and forms epoxides but the preference is just the other way i ...
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On what factors does the strengths of electrophiles & nucleophiles depend on??? ...
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Can someone give me the following 2 mechanisms? 1) Mech of DDT formation from Chloral and Chloro-Benzene 2) Mech of Di-oxane formation from Glycol in presence of fuming Sulphuric acid... ...
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1) In a book it is said that in the dehydrohalogenation of alkyl hallide to form alkene, if the alkyl hallide contains only one β-carbon atom then only one alkene is formed.And they have sited this example CH3 | CH3-C-Br + a ...
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if i add it across CH3NH2 *Image* will i get cis 1,2 dimethyl cyclopropane or trans 1.2 dimethyl cyclopropane?????????????????????? ...
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-NH2 gr. shows acidic nature while reacts with reagent-- A. Na B. CS2 C. Br2 + NaOH D. Water ...
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why compactness decreases the boiling point and increases the melting point of a structure????????????????????? ...
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Why is SN1 reacn carried out in polar protic solvent? ...
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pLZ any organic tip here.......like how to increase, decrease Carbon atom , distinguishing between compounds , solving word problems, etc etc... ...
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i read tht if secondary alcohols when vigriously oxidised in kMnO4 gives acit...but whn we use bwrd vigrious do we mean heating it?/? ...
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for stereoselective reactions is it necessary to have a chiral object which imparts influence?????????????? ...
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Which solution is a stronger acid ?? HCl dissolved in water or HCl dissolved in benzene ?? Ans should be water no..because H+ can be more furnished there, ...
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CHCl3 is polar but still insoluble in water. Why ? ...
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Whenever we do an anti- Markonikov addition (using peroxide), we always use HBr and not HCl or HI...... Why is that??? (I don't know...u tell me) NOTE: Another thing to "ponder" :P How do we spell the name of the scientist??? ...
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Plz post some good conversion problems here. ...
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May i know the atomic orbitals of the same atom will interfer each other. That is the s orbital of the atom chlorine interfers with its p orbital. ...
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are paladium charcoal and selinium in conjuation wth olready existing double bonds ? dey r d organo metallis compounds...actually d thng is m rili confused in dis part of organic .. n wht is d reactivity order dey follow? ...
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are paladium charcoal and selinium in conjuation wth olready existing double bonds ? dey r d organo metallis compounds...actually d thng is m rili confused in dis part of organic .. n wht is d reactivity dey follow? ...
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ARRANGE IN INC ORDER OF STABILITY WITH EXP PLS :CH2 , :CF2 . :CCl2 repeat same if they were triplet carbenes!!!!!!!!!!!!!!! ...
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an unequal mixture of l and d isomers of synthetic camphour are present in a soln. which shows a specific activity of -13.9 .............. find the enantiameric excess!!!!! helllp ...
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is racemic mixture a chiral object ...
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some doubts: 1. why does basicity and nucleophilicity decrease across a period?? 2. why are para products preferred in low temperatures in phenolic reactions?? 3. explain mechanism of this reaction: R-Br + Ag20 → R-O-R ...
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wht does SeO2 do..?????? ...