Ans not matchin

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The following compound

treated with AgNO₃ and H₂O ??

#Chemistry #Organic Chemistry

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9 Answers

39

Pritish Chakraborty ·2009-10-27 02:21:07

In place of Iodine you will get -OH group, and Ag will abstract the halogen atom and form a precipitate. AgI ppt is insoluble in ammonia solution of any concentration, that's how you test for it.
Thus you will get HNO₃ and AgI as byproducts.

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11

Gone.. ·2009-10-27 02:25:16

thats what even i got..but thats not the ans given .

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39

Pritish Chakraborty ·2009-10-27 02:34:56

Well the carbocation cannot rearrange to a secondary one as the bridge head carbon cannot be planar. But Ag will leave primary carbocations with no mercy, the mechanism will go forward. Can you post the ans?

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11

Gone.. ·2009-10-27 02:38:54

ok..wait a sec

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Gone.. ·2009-10-27 02:41:23

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39

Pritish Chakraborty ·2009-10-27 02:41:52

Maine toh yahi kaha tha?? iodine ke jagah -OH?
Ahh..wahan pe rearrangement kaise hua?

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Gone.. ·2009-10-27 03:18:22

how did xtra carbon come ??

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39

Pritish Chakraborty ·2009-10-27 04:52:43

Wahi..possibly a misprint?

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Gone.. ·2009-10-27 05:50:30

okie...

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Your Answer

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