Organic Chemistry - carbene

1

vector ·2009-02-17 01:58:19

YA

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vector ·2009-02-17 03:58:55

[[/img]
compare rotational free energy barrier?

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voldy ·2009-02-17 04:00:13

well these are alkenes what rotation ?

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vector ·2009-02-17 04:37:35

DO NT U KNOW WE CAN REPLACE =WITH +-----_ to check rotation barrier

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msp ·2009-02-17 04:40:27

wats the question richa

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vector ·2009-02-17 04:43:58

compare free rotational energy barrier also check d explaination given by u in markonikoff q i m not satisfied by ur ans check my post

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62

Lokesh Verma ·2009-02-17 05:02:47

bhargav.. I dont think you have any right to make any such comment.

please make sure this is the last time you are posting such a comment for nay user.

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39

Dr.House ·2009-02-17 05:04:42

i am really sorry. i deleted it. that was the last time. sorry again.

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vector ·2009-02-17 05:08:42

sum1 plzzzzzzzzz try

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33

Abhishek Priyam ·2009-02-17 05:09:04

well the lesser the double bond character the lesser the free rotation energy barrier...

max for(d)

and for rest [12]

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33

Abhishek Priyam ·2009-02-17 05:09:35

min for (a)

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vector ·2009-02-17 05:11:31

right try others

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vector ·2009-02-17 00:45:50

i had made d structure n tried to upload it.plz tell d reason if u know.

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Abhishek Priyam ·2009-02-17 05:14:24

oh min for c.. ok [12] rest i am trying... "i am trying organic chem..." hehehehe

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33

Abhishek Priyam ·2009-02-17 05:15:14

(d)>(a)>(b)>(c)

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vector ·2009-02-17 05:16:24

how??????????

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33

Abhishek Priyam ·2009-02-17 05:18:22

because u told that it is min for (c) and i was thinking it to be (b) so
(b) must be slightly less than... (c).. hehehe [3]

ok i am posting something.. wait a min.. but i still feel for (c)>(b)

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62

Lokesh Verma ·2009-02-17 05:19:14

great question and i think great answre as well :)

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vector ·2009-02-17 05:19:38

i did not understand why c is min?

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33

Abhishek Priyam ·2009-02-17 05:26:52

i really feel...(that was tukka..)

what i am getting 'legally' is
(d)>(b)>(c)>(a)

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Abhishek Priyam ·2009-02-17 05:28:17

sorry if my tukka matched...i don have any reason for that...

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skygirl ·2009-02-17 05:35:34

i think ans should be d>a>c>b ..

wats the ans ?

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vector ·2009-02-17 05:36:20

Nishant sir, plz help n explain d reason .

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skygirl ·2009-02-17 05:47:33

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skygirl ·2009-02-17 05:48:55

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