Expalination

In addition of DBr to 1,3-cyclohexadiene,2 products are obtained.What is best explaination for formation of B???

11 Answers

1
voldy ·

pi -electron shift that's all

24
eureka123 ·

yup u r rite..........can u explain it with help of diag ?????

39
Dr.House ·

come on eureka tihis one is damn eaasy.

its a conjugated diene system, so 1,4- addition is obvious

39
Dr.House ·

sry didnt see the post before

24
eureka123 ·

yeah got it...............tahnx everyone....[1]

39
Dr.House ·

at high remperature 1,2 product is more favoured

in general, at low temperature we get product controlled by chemical kinetics where as at high temperature we get a thermodynamics controlled prduct

1
voldy ·

hopefully this suffices. :)

24
eureka123 ·

whats that +1/2 and -1/2 ??????????does that signify equal probablity of attack or equal distribution of positive charge on conjugated system???????[7]

1
voldy ·

no , It' signifies that the charge is distributed over the 2 carbons equally.
remember SE reactions ? That's y I wrote not totally correct.

24
eureka123 ·

ok.....thanxxxx[1]

19
Debotosh.. ·

1,2 product :A: kinetic product
1,4 product :B: thermodynamic product

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