FRiedel crafts rxn

Toluene is treated with Cl-CH-CH2-COCl
l
CH3
in the presence of anhydrous AlCl3 The product formed is

Here friedel craft acylation will dominate or acetylation

43 Answers

13
deepanshu001 agarwal ·

acylation shud dominate

21
tapanmast Vora ·

thn wats da ans now!

is it ACYLATION/ACETYLATION

1
karan9989 gupta ·

ans is according to alkylation at p position will preceed acylation

21
tapanmast Vora ·

acylatn

1
karan9989 gupta ·

Both are taking place But the problem is which of them will preceed

13
Двҥїяuρ now in medical c ·

i mean........take place simultentously forming a single product...both ends joined to the ring

1
greatvishal swami ·

dont expect so much of toluene abhi [9][9]

after all its not so strong +R group

1
skygirl ·

alkylation shud be preferred.......

21
tapanmast Vora ·

y?

IS IT A rule or sumthing?

1
skygirl ·

no no...

wen Cl leaves, C+ in c=o is less stable then c+ in -C-CH3-C=OCl [y pata hai shayad.. aurtype karne ki mood nahi hai :(]

dats y told this.....

wen there is no option for alkylation.... then acylation is only way!

21
tapanmast Vora ·

Ha ha.. [112]

okie....

1
voldy ·

acylation favored as carbonyl carbon is more stable .

1
voldy ·

I mean carbonyl carbocation.

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