1
kartik sondhi
·2009-09-25 06:17:40
As it is A Primary Amine it Will Form A Stable Product This One
24
eureka123
·2009-09-25 06:20:29
had the answer been that simple I would never have posted this here...
1
aieeee
·2009-10-03 00:26:38
actually , its a pinacole-pinacolone type reaction. u must be wondering how ?
wherever ders an -OH group adjacent by a positive charge , then pinacole-pinacolone type reaction cn take plce ( provided : der must be some migrating group attached to the carbon to which -OH group is attached. )
here HNO2 group displaces NH2- group and a +ve charge appears. then pinacole-pinacolone reaction takes place.

1
RDX
·2009-10-03 09:16:16
no.. wait.. it is special kind of reaction.. ring expansion takes place here for sure... but I'm not able to recollect that reaction at all..
1
RDX
·2009-10-03 09:17:13
oh.. ok. okk.. I think aieee did that only.. It's Demjanov reaction.