multiple answers dbt

in which of the following decarboxylation takes place on simple heating ??

ans is 1,3
but why not 1,2,3 ??

8 Answers

1
rahul nair ·

2 is B-keto acid....so even i think its 1,2,3.....

1
aieeee ·

i think its just 1,2 !

in 1) ders C=C at the \beta - position.

in 2) ders keto group at \beta - position

in 3) and 4) , ders C=C at the \gamma - position

thus, at 3) and 4) , der can't be decaboxylation by simple heating.

24
eureka123 ·

but anyways ans is 1,3

1
aieeee ·

but why 3 ) ?

24
eureka123 ·

3 should be naa....resonance.... π-σ-π

1
aieeee ·

perhaps u r mentining this

24
eureka123 ·

no i was mentioning option 3

24
eureka123 ·

ok thx everyone......
ans is 1,2

it was my mistake...[2][3]

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