Organic Chemistry - nitro cpds 2

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msp ·2009-01-26 08:04:49

HOWEVER IT IS 296TH PAGE

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msp ·2009-01-26 08:27:33

oops no coordinate bond wil be present it will be a hybrid structure

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prateek punj ·2009-01-26 08:27:07

hey can u please post the image of the previous page of this post....

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msp ·2009-01-26 08:22:25

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prateek punj ·2009-01-26 08:21:31

In NO₂, there is one cordination bond between N and one O.....that is obvious....

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msp ·2009-01-26 08:19:37

U CAN SEE DAT THERE IS NO COORDINATE BOND IN THE DIAG

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prateek punj ·2009-01-26 08:18:44

yaar, in first figure it is becoz of coordiation bond only......

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msp ·2009-01-26 08:17:14

NOOO

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Harry Potter ·2009-01-26 08:16:56

yess prateek rite

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prateek punj ·2009-01-26 08:11:04

yaar, that positive and negative charge r due to the co-ordination bond formed between nitrogen and oxygen.....

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msp ·2009-01-26 08:09:29

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prateek punj ·2009-01-26 08:07:58

does the positive charge on nitrogen develops due to transfer of lone pair of nitrogen to oxygen.....

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msp ·2009-01-26 08:07:14

PLEASE WAIT DA I CAN POST THE PHOTO OF THE PAGE

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msp ·2009-01-26 07:42:25

relp.........

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prateek punj ·2009-01-26 08:04:35

tell the topic in which it is mentioned....

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msp ·2009-01-26 08:03:50

yup i have old NCERT

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prateek punj ·2009-01-26 08:00:44

can u please tell the page number in NCERT.....

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msp ·2009-01-26 07:59:39

but in NCERT the resonance structure of RCH2NO2 will have a partially positive charged nitrogen

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prateek punj ·2009-01-26 07:58:07

thnx.....

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skygirl ·2009-01-26 07:56:14

yeah ... nice prateek :)

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prateek punj ·2009-01-26 07:52:32

@sankara,

hey yaar,

Since oxygen is more electronegative as compared to nitrogen therefore, the tendency of oxygen to give it's electron to H⁺ as compared to nitrogen will be less....
Therefore H⁺, acc. to me should follow the path 1.....

Also, since the electrons are delocalised in case of oxygen, therefore electron density at oxygen is less as compared to that of nitrogen.....

Also, due to +I effect of R-CH₂ group the basicity of nitrogen is also increased....

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skygirl ·2009-01-26 07:50:44

sry [3]

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skygirl ·2009-01-26 07:50:25

y will H+ attack ? [3]

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prateek punj ·2009-01-26 07:48:12

kkkkkk

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msp ·2009-01-26 07:47:46

yes prateek but these electrons are delocalised so i drew the diag like dat

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prateek punj ·2009-01-26 07:46:41

hey buddy the second path u have mentioned is the attack of H⁺ on lone pair of oxygen or something else.....

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