Reagentss.........

What reagents (think of all possible reagents that can be used) which can perform this conversion successfully ?

I know three;lets see how many you can think of !![6][6]

19 Answers

1
MATRIX ·

yaar rkrish H2/Ni or Pd will reduce it yaar(it would be better if Ni or pd are finely Divided )........:P.........

1
skygirl ·

no i dun think here it will.......

cause if H+ ataches to O, any one bond will break.. resulting in + charge in one of the double bonded carbons..
which is very very unstable..

1
ANKIT MAHATO ·

how about NaBH4 + H+ ... i am not sure whether it will reduce the O in the chain ...

1
big looser ......... ·

MnO2

11
rkrish ·

ok fine...sry.....but it wud reduce C=C also!!!

13
deepanshu001 agarwal ·

krish u didnt get me i meant pd wont reduce CHO but NI wud...

11
rkrish ·

@MATRIX

for post #11

Now what do you say [7][7][7]

11
rkrish ·

@MATRIX...

for post #9...

I know that "...(Evrybody nows that ).:P..." BUT

HOW CAN YOU USE A GRIGNARD REAGENT WITH THE GIVEN SUBSTRATE,TO GET A 1° ALCOHOL ?????????????

1
voldy ·

LAH

13
deepanshu001 agarwal ·

Ni wud reduce it ... but Pd wont....

1
MATRIX ·

One of the Reagent is Grignards Reagent........

1
°ღ•๓яυΠ·

Na -Hg in alcohol

1
MATRIX ·

for reaction with Grignards Reagent it will be a form a complex or in other words an "Adduct"........and on further reaction with water it will form the correspondin aldehyde and give back Grignards Reagent.........
and Grignards Reagent General Formula----->RMg(OH)X(Evrybody nows that ).:P...[3][3][3].....

1
MATRIX ·

hey rkrish this is a reduction process .........reduction of a alcoholic group to aldehyde group so for redution process to take place we need reducing agents.......

11
rkrish ·

@MATRIX...
1)post #2 : can you elaborate a bit?
2)post #3 : H2/Ni or Pd will also reduce C=C
3)post #4 : can you give specific examples?

1
MATRIX ·

krish check if ma answers are correct.....

13
deepanshu001 agarwal ·

giv the options if u hav them...

1
MATRIX ·

We can use any(not sure any may be some) mild Reducing Reagents for this Reduction Purpose........

1
MATRIX ·

Then the Second one is add H2 to alcohol in Presence of Finely divided Palladium or Nickel.....

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