11
Mani Pal Singh
·2009-04-03 08:26:09
inversion in the product certainly ring the bells 4 the SN2 and SN1 is ruled out
i think that
SOCl2 + Pyridine and HBr or HI should bring the inversion of the products as per the reason mentioned [1]
11
rkrish
·2009-04-03 08:58:29
R--OH + PCl5 , PBr3 , SOCl2 or SO2Cl2 -----with base-------> X--R
R--OH + PCl5 , PBr3 , SOCl2 or SO2Cl2 -----without base-------> R--X
eg. of base : Pyridine , R3N , etc.
And as mani said , Inversion means SN2 (BUT with few exceptions as above.)
SN1 means Retention in configuration along with Racemization.
21
tapanmast Vora
·2009-04-07 05:22:23
ARE THER ne MOR conditns to it dependin oon solvent???
1
prateek punj
·2009-04-07 05:28:35
arey yaar SOCl2 aur pyridine ke combination main bhi inversion of configuration ke chances hote hain... SNi mechanism....
1
prateek punj
·2009-04-07 06:14:59
yaar i think it can also be the case...
1
Aditya
·2009-04-07 08:03:23
I think in SNi mechanism there is only retention.
1
sanjay_dixit b
·2009-04-07 09:00:58
are yaar when we use socl2 with pyridene there will be generation of strong nucleophile cl- with the reaction of formed hcl from h+,cl- in the first step and pyridene hence the reaction changes to sn2 and there will be inverted pdct
1
prateek punj
·2009-04-08 04:42:33
maine kaha tha SNi main inversion hoti hai....