RTPF Assertion Reason

S1 : A mixture of primary,secondary and tertiary amines is formed in good yield by heating carbonyl compounds with NH3 and H2 in presence of a catalyst.

S2 : The eqb. constant for addition of NH3 to all carbonyl compounds are very high.

IS S1 correct ?? "Good yield" is obtained ??

4 Answers

39
Pritish Chakraborty ·

Good yield is obtained only when excess of ammonia is used...so with normal quantities of ammonia we do not get a good yield. I think S1 might be false and S2 is true.

11
Gone.. ·

I thought so..

Ans given C..(S1 true,,S2 false)

39
Pritish Chakraborty ·

lola...I don't remember ammonolysis of carbonyls. Have to read it again.

11
Gone.. ·

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