39then ok dude. sorry to u.
1)Acetic acid,when reacts with excess of HI in presence of red phosphorous gives___
2)wat is the product obtained ,when ter-butyl chloride, on reaction with Na metal _______
3)Reduction of propanol with HI and red P yields ____
please reply with reasons and tx in advance
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21 Answers
24ya got it now...........wurtz reaction does not take palce here..becoz its tertiary halide............and tertairy halides dont participate in wutrz reaction due to least stable carbanion..............i dont know why i didnt get that before......[2]
21OH yah,
and @mathematician
I had read the questn as red P, I2 which results in Hell Volhard Zelhinski reactn..... otherwise it was obvious ethane!!!!
39tapanmast i say u better have a gud look at organic once again yaar, u r having many conceptual flaws.
by the way the first one is obviousle ethane. red P + HI is a famous reducing agent. not only carboxylic acids but it also reduces aldehydes and ketones into coresponding alkanes.
24u r wrong in first step only.......e attacks not Na+....i suppose...[12]
24ohhh...[3]
R3-C-X->R3-C-.......
formed becoz a free radical accepts elcetron
3does carbanion is the intermediate in wurtz reaction.
wont the free radical will be the intermediate
3both da according to the buk.
but according to me he is correct for the 2nd question
3eureka123 ok i have left the solvent for the 2nd question it is given as ether da
guys i want the explanations pls give.
but tapanmast u have given rong ans according the buk da but u and eureka were rite for the 3rd question
24But dry ether is not given...........so how can Wurtz reaction take place?????????[7]
212reasons :
1) No other produvt seems likely ([3])
2 moles of tert butyl alc. + 2 Na ---> product + 2NaCl.....
Sankara can u confirm if my ans's rite or not???
211) CH2ICOOH [ *EDITED]
2) (CH3)3-C-C-(CH3)3
3) wat euereka said....
242)Is there any solvent???[7]
I think its difficult to predict otherwise.....[2]