some concept related to stereoisomers

what are rotamers

what is the axis of symmetry in configurational isomers

7 Answers

11
Subash ·

are you sure this is in syllabus ive never heard of it

1
ANKIT MAHATO ·

Conformations are not superimposable in three dimensions and can be characterized by their dihedral angles, the angle between two planes formed by atom1-atom2-atom3 and atom2-atom3-atom4 in a sequence of atoms, atom1-atom2-atom3-atom4. The dihedral angle can also be seen as the angle between the two vectors formed by atom2→atom1 and atom3→atom4. Rotamers are conformers that differ by rotation about only a single σ bond. That is, only one dihedral angle will be different between rotamers.

1
ANKIT MAHATO ·

but there is no harm in knowing .. because we have actually studied eclipsed form and staggered form of ethane and these two are actually rotamers :)

1
karan9989 gupta ·

thanks Ankit
please also explain the axis of symmetry
i only know about the point and the plane of symmetry but what is this axis of symmetry

11
Anirudh Narayanan ·

hey ankit, beautiful pics, man

1
karan9989 gupta ·

Hey its asked in iit 2008 about the axis of symmetry
Please someone help

1357
Manish Shankar ·

axis of symmetry is a line about which if you rotate the compound
you should get the same compound at some angle of rotation (angle should not be a multiple of 2nπ)

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