sum more views reqd:)
do aromatic alcohals n alpha hydroxy ketones give tollen test?
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26 Answers
i think its because of the M and I effects shown by the -OH when placed at ortho meta and para position, i dont have any other idea.
actually catechol n resorcinol do not give d test n hydroquinone is giving test cud u explain
the answewr lies in the question u asked. if aromatic alcohols are oxidisable, then this will also be oxidisable. as u know it is a aromatic di-ol na.
ab , mujhe jo pata tha batha diya, aage i will have to see if the compound is easily oxidisable etc etc.
@akand, u only try, the clue i can give is that C2-C23 centre is very easily prone for oxidation
@manipal: i donno from where i read it, its been long i stopped organic. i think it was given by our sir.
alcohals,ketones---->tollen test
maine pehle kabhie bhi nahi suna
jahan tak mujhe pata hai it is given by aldehydes only
@manipal.. there is no need to think for a source here.
think in terms of the process.. the alpha hydrogen is available for exchange..
dude, woh tho depends na........
i cant definitely say just alcohol will get oxidised to ketone, and actually it depends, but
watever information i gave, its right, i am damn sure
in your question, aplha hydroxy ketones gice it because
two adjacent carbons, one containing carbonyl and other contains alcohol. this is very easiiily prone to oxidation.
wel i dont think so........... i dunno about d second one but 1st one definitely no...
the following give tollen`s test, kindly remember if u can
1formic acid
2all formates
3alpha keto carboxilic acids
4alpha hydroxy carboxylic acids
5alpha hydroxy ketones