106
Asish Mahapatra
·2010-03-20 05:59:03
Disclaimer: All the statements written below are purely the work of my imagination and cant guarantee any relation to known facts.
Look at your own risk
Thinking (A)
stronger acids => more unstable (as more dissociation)
(horribly wrong statement I hope)
therefore A
4
UTTARA
·2010-03-20 06:29:38
I say (a)
Because I think the other options r stabilized due to + I effect
My reason may be wrong Din't revise organic yet : (
21
amit sahoo
·2010-03-20 06:59:14
i will also go with (A) because it has two adjacent c=o bonds......so it will be unstable.
39
Pritish Chakraborty
·2010-03-20 07:18:05
How does that make alpha-keto acid unstable?
I don't think we can use conjugate base concept here...that is to decide acidity. On warming(not even full-on heating), beta-keto acids quickly decarboxylate by means of six-membered transition state. So I go for (b)..can't think of anything else.
Eure please confirm.
11
Tush Watts
·2010-03-20 10:05:35
wat abt Mesomeric effect guys ???
24
eureka123
·2010-03-20 11:38:53
ya ans is b....
thx priritsh,for confirming that we had to attempt using beta keto acid concept[1]
1
JOHNCENA IS BACK
·2010-03-20 14:25:50
haha!!!!!!!i was damn sure i got this wrong [1][1][1]