what is meant by positive and negative phase in an orbital
the blue part in the figure is known as positive phase and orange part is known as negative phase.What do these signify with respect to struture??
do these phases have any relation with electron density at a particular place in orbital?
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3 Answers
6Light waves can interact in-phase, which leads to an increase in the intensity of the light (brighter) and out-of-phase, which leads to a decrease in the intensity of the light (less bright). Electron waves can also interact in-phase and out-of-phase. In-phase interaction leads to an increase in the intensity of the negative charge. Out-of-phase interaction leads to a decrease in the intensity of the negative charge.
One of the ways the atomic orbitals interact is in-phase, which leads to wave enhancement similar to the enhancement of two in-phase light waves. Where the atomic orbitals overlap, the in-phase interaction leads to an increase in the intensity of the negative charge in the region where they overlap. This creates an increase in negative charge between the nuclei and an increase in the plus-minus attraction between the electron charge and the nuclei for the atoms in the bond. The greater attraction leads to lower potential energy. Because electrons in the molecular orbital are lower potential energy than in separate atomic orbitals, energy would be required to shift the electrons back into the 1s orbitals of separate atoms. This keeps the atoms together in the molecule, so we call this orbital a bonding molecular orbital. The molecular orbital formed is symmetrical about the axis of the bond. Symmetrical molecular orbitals are called sigma, σ, molecular orbitals.
The second way that two atomic orbitals interact is out-of-phase. Where the atomic orbitals overlap, the out-of-phase interaction leads to a decrease in the intensity of the negative charge. This creates a decrease in negative charge between the nuclei and a decrease in the plus-minus attraction between the electron charge and the nuclei for the atoms in the bond. The lesser attraction leads to higher potential energy. The electrons are more stable in the 1s atomic orbitals of separate atoms, so electrons in this type of molecular orbital destabilize the bond between atoms. We call molecular orbitals of this type antibonding molecular orbitals. The molecular orbital formed is symmetrical about the axis of the bond, so it is a sigma molecular orbital with a symbol of σ*1s. The asterisk indicates an antibonding molecular orbital.