electrochemistry

Why reduction potential of reducing agent decreases with rise of temp. & with increase in concenteration of the reducing solution ?

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kartik sondhi ·

with the inc. in conc. hindrance in the sol. increases ionic mobility decreases and hence reduction potential decreases
rise in temp. Δ G = -nFE = ΔH-TΔS where E is a func. of (H,T,S) therefore reduction potential decreases

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