IIT JEE past question Kinetics 3

The rate of first order reaction is 0.04 mol L-1 s-1 at 10 minutes and 0.03 mol L-1 s-1 at 20 minutes after initiation.

Find the half life of the reaction.

5 Answers

1
Philip Calvert ·

n1/n2 = 4/3

n1 = n0e-λ10

n2 = n0e-λ20

dividing we get

4/3 = e10λ

10λ = ln (4/3)

t1/2 = 10 ln 2/ln(4/3)

something like this [7]

62
Lokesh Verma ·

tapan see carefully it has to be more than 10 minutes!

62
Lokesh Verma ·

tapan is it 2 half lives?!! :O

21
tapanmast Vora ·

Got my mist.....

I had taken rate as the CONcentration [16] [17]

1
Philip Calvert ·

24min perhaps [7] oh i am messing up with the final calculation
give me a break !!

ya now 24 looks more close to the answer

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