IIT JEE past question Kinetics 8

at 380 degree C, the half life period for the first order decomposition of H2O2 is 360 min.

The energy of activation of reaction is 200 kJ/mol.

Calculate the time required for 75% decomposition at 450 degree C

1 Answers

11
Mani Pal Singh ·

t1/2 =0.693/k

k380=0.693/(360)

now
k1/k2=Ea/RT (1/T1-1/T2)

FROM HERE WE CAN FIND K450 AS EVERY INFO IS PROVIDED

k450=1/t 2.303 log [a]0/[a]

k450=1/t 2.303 log4

solving this equation we can get the time period

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