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when 60.26g of VCl4 was added to 1000g of solvent,freezing point of solvent was depressed by 5.415°.Kf=29.9.calculate the no. of dimers,V2Cl8 .
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5 Answers
Manish Shankar
·2009-04-06 22:12:09
moles of VCl4 initially is n=60.26/193
VCl4---------------->V2Cl8
n 0
n-α α/2
total moles at equilibrium=n-α/2
initial moles=n
i=(n-α/2)/n=1-α/2n
ΔTf=ikfm=iKfW/M
i=MΔTf/WKf=1-α/2n
α/2=n-ΔTf/Kf=0.13 moles