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Nitrobenzene is formed as the major product along with a minor product in the reactionof benzene witha hot mixture of nitric acid and sulphuric acid. The minor product consists of carbon: 42.86%, Hydrogen:2.4%, nitrogen:16.67% and oxygen:38.07%

i) calculate the emprical formula of the minor product
ii) when 5.5 g of the minor prouct is didsolved in 45 g of benzene, the boiling point of the solution is 1.84 degree C higher than that of pure benzene. Calculate the molar mass of the minor product and determine itsmolecular and structural formula.

Molal boiling point elevation constant of benzene is 2.53 K kg/ mol

2 Answers

21
tapanmast Vora ·

EMP formula : C3H2NO2

aage karte hain.....

21
tapanmast Vora ·

Assuming no dimerization & no diss. we get x =2;

So MF = C6H4N2O4

matlab : structural formulae :

o,p,m disubstituted NitroBenzene

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